I didn't know that you had them machined flat already. I thought that they were used just taken off an engine and cleaned up (grease/carbon wise).
I would use the second one with the 60 cc chambers, as it was more consistent. The other one will still work on a daily driver, 1 cc won't make a noticeable difference.
I would do any porting first, just in case the seats may get accidentally knicked. It's best to do the porting before the valve job.
Then get the oversize valves installed.
Too bad you're not closer, I know a guy near Detroit that does good porting and valve jobs reasonably. (He gives good head - LOL!)...