Any electrical guru's know off hand what these are for?

The washer pump got only one wire, brown I think.

Correct. Some could be for the pollution control perhaps ?

Is the car running at the moment ?

What you need is the Chrysler repair manual , book 2. Along with schematics, they actually diagram each connector.

I see the two manuals are available here:

http://www.mymopar.com/index.php?pid=109

Good luck with the wiring...it can be a beast !