Trying to get the heater working

Thanks guys! Do you mean that with the selector switch in the off position, the valve is closed so that no water flows into the core?
Yes, it blocks the flow into the core in the off position, and the same without vacuum connected to the valve. It takes a vac source to open it. That doesn't mean the hoses and core don't have coolant in them though, just that hot coolant can't be circulated through the core and produce heat inside the car.