Am I ok with this? KB107 in La block

Yes it appears to me that one sticks out that much and the other is below that much.
OK, there are plenty of suggestions for the difference in deck height. I have nothing to add there. But to address your second question: Yes you can. Factory 340 high compression pistons (68-71) came out of the hole .015-.025 and they cleared the open chamber X and J heads even with thin steel shim head gaskets. Those pistons are the reason why Edelbrock offers their 340 aluminum heads in a large chamber version which is just the regular RPM head machined the diameter of the cylinder some .060 inch - just to clear pistons with a positive deck height.
Thank you! The shop that took my j heads and installed 2.02 valves for me machined them a bit they are shiny and straight. I have no way of knowing how much they took off and if it's still safe.