Well......not really. The upper arm adjustments affects both castor and camber. You could set toe pretty easy enough to herd it down to the alignment shop.
You can Google front end alignment, and there's all sorts of caster / camber gauges if you want to learn it yourself.
Some articles:
http://www.carcraft.com/howto/48938/index.html
http://www.allpar.com/fix/alignment.html
http://www.hotrod.com/techarticles/chassis/hrdp_0411_wheel_alignment_guide/index.html