Cant wait to start working on my Duster, but need lots of help!!

Welcome
Thanks for your service, this cant be said enough!
The first thing you have to determine is are you going to put this right on the road or work on it for a while?
If your putting it on the road do the brakes first.
Depending on how long it sat, drain the fuel and purge the system, change ALL the fluids and then get it on the road.
If its going to be put on stands and worked on first, grab a beer read through posts and make a list on paper, then attack the list.
It looks like you have a great starter vehicle, and you have come to the right place
Andrew