V6 vs V8

My 3.6 v6 that makes 288 hp has 11.5:1 compression and uses 85 octain just fine. That is somewhat the VVT but also a lot of the direct injection. Now they can even eliminate the throttle plate all together and control rpm and ignition with fuel like a diesel. With the VVT, the can timing itself can be constantly adjusted, there are even aftermarket tunes to replicate a "thumper" can by adding overlap whenever you want, or a velvet smooth idle. The 4 valves per cylinder means a Hemi style chamber with opposed valves but also a larger overall surface area for airflow but the individual smaller vavles mean less shrouding then 2 large valves.

The main thing is the fact you have 2 separate intake ports with much higher velocities than one bigger one. A Hemi chamber doesn't have an issue with valve shrouding but using massive valves/ports to take advantage of the layout makes the airflow sluggish at low speeds.

There are "levels" of VVT also, the only kind that can make the full adjustments for cam overlap are the ones in DOHC engines. SOHC and pushrod engines like the new Hemi can only advance/retard the overall cam timing, except for others (Honda VTEC) that can actually switch between two different cam profiles while running.