There's also the electrolysis issue. Bad groundings, lack of grounding, attaching ground straps where convenient rather than where intended. All can cause even 'good' coolant to show issues. Water isn't the fault here, though a more dielectric coolant might stave off the issue, the real problem is a poor electrical system. This is a problem on many hot rods and home-built cars because it's simply not understood. Electric potential in the cooling system will corrode parts no matter how many inhibitors are present. Minerals and contamination in the added water will accelerate it.