471 Big Block high rpm problems

0 DEGREES TDC mark on the distributor where #1 terminal is and #6. Remove the cap and see how the rotor corresponds to which ever mark it is pointing to. If it is not dead on or just a hair after you may have an issue. If it is closer to the next terminal in the firing order you may be able to get away with rewiring the cap.....
Will check it today and post some info.