Yup.
"Moly" rings are iron rings, with a molybdenum coating applied to the wear surface that contacts the cylinder wall. It's only the top ring that gets it, because that's the one that is designed to seal compression. Moly faced rings need a smoother wall finish than iron faced. Much smoother to really do what they are supposed to, which is seat immediately. Moly does nothing else but seat much faster with the right wall finish.