Finally, my first 360 and goals for it! I'll be asking a lot of questions.

Replacing the valve guides and cutting the seats is a job for the machinist, the right tools & experience. If you stay stock type replacement valves, they can be had in oversize
stems, & the guides are reamed/honed .005" or .010" over to accept them. If you replace or resize the guides you will automatically need the seats re-cut........& no, don't let
someone talk you into knurling & reaming the guides.
Not sure I follow you here. I could get valves with oversized stems and make them work with some work on the existing valve guides ? Or I could re use my old valves and have new guides installed?