Home made fan shroud.

They call it a radiator because it RADIATES heat. There is a big difference in the amount of radiation based on color and temperature difference. Paint conducts heat and then radiates it from its surface depending on its color. If air is hotter than the surface, a black color then absorbs the heat while a white color reflects more heat and absorbs less..
I agree that the color of the shroud won't make much difference. The color of the tadiator would.