It's not necessarily that it's all boiling out of the bowl, it's that modern fuel expands very easily with heat. Most of the time it expands into the manifold through whatever passage is most convenient, and when it hits that hot manifold, it vaporizes. Therefore, when you go to start it hot, you have a pig rich mixture pumping through there until the engine can clear it out.
Phenolic spacers can help, and adjusting your starting method can help. Crank it for a second with your foot off the gas, then slowly push your foot to the floor like you have a flooded engine (because you do). Make sure your choke unloader is working. Usually, the engine will catch within a couple seconds.
