Putting head on slant six

is .013 the intake and .023 the exhaust for valve adjust?

Those are "get it in the ballpark" cold settings. The final settings are 0.010" intake and 0.020" exhaust hot and running; see valve adjustment procedure. Also see tune-up parts and technique suggestions in this post. Carburetor operation and repair manuals and links to training movies and carb repair/modification threads are posted here for free download.