Not your normal Mopar cooling issue

It will only collapse if there isn't any pressure in the system, as is a bad radiator cap. Does the system make pressure when the temp comes up ?
I agree with all the comments above but one that was missed is that you may have a 'volume' issue. With a big motor and a small radiator at higher speeds, you don't have an air flow issue. The air is pushing through the radiator faster than any fan combination that exists. If you can get more fluid in the system, you can lower temps at speed.
I'm using this radiator from engineered cooling 22" Mopar BIG BLOCK HD Aluminum Radiator - Dual Fans And Aluminum Shroud and a milodon high flow water pump so I'm not sure fluid is an issue, but maybe.