First of VIN is V8, does this indicate V8 engine?

Nope, it's more confusing than that. 31 can be either two or four barrel depending on the year. '65 it's a four barrel, '66 it's a two barrel. 32 is four barrel in '66. Formula S is a different code down that line. '64 only had one 273 available and that was 30.
How the heck do you know all this, LOL! Thank you for sharing!