Slant Six 170 vs. 225

Question, when was the first un-leaded head made? I have 5- /6s and thinking hard on using one in my 69 notch.
I'm not positive. But what difference does it make? If you're swapping heads, any way, you should do a valve job on the head. The factory hardened seats are only a few thousands deep, and a valve job removes the hardened surface. I would suggest installing hardened exhaust seats during the valve job, if you're looking for longevity.