Valve choices

The top of the bore is an extension of the chamber, & can be relieved in kind above the ring travel, done it on other similar long-stroke smaller-bore mills. De-shrouding is key to large valves. At higher lifts the side shrouding encourages swirl depending on port orientation, and the form that is cut.
...and no, it's not "just" the top of the cylinder. The WHOLE cylinder is the chamber.