Overheating issues

To say a system is not vented when it has a pressure release cap simply isn't true. The pressure valve on the cap IS the vent. As for the overflow tank, the same applies. If it has a pressure release cap, it IS vented, it is just NOW an extension of the radiator tank
The radiator cap is vented no argument there.

BUT... If the overflow bottle does not have a vent or a pressure cap then the entire system is no longer vented.

On top of that, if the overflow cap is a pressure cap at 16 lbs and the rad cap is 7 lbs the system is 16 lbs