Swap pistons for quench?

Checked my heads and they need some additional work. I just measured the cc’s in one chamber so far, but depth of the chamber in one head varies from 30 to 40 using straight edge and feeler gauges. I planned to clean them up from 30 years of sitting so I can even that out to with a clean up cut and grinding some from the one hole that’s 30. The other head is about 60 in all four. Pending how the cc looks like I will need to mill around 20 more on that side. Oldmanmopar says I need more compression. What can I run with say 35 quench in iron heads on 94 octane.
More compression than "WHAT"? How do you know you need more compression unless you measure what you have now?

Also, what are your plans for the car? Street car? If so, the last thing you need is to push the boundaries of pump gas driving around hung up in slow or stalled traffic in 90 degree plus weather. There are plenty of ways to tune a lower compression engine to run. Don't get hung up on this without knowing exactly what you have now.