The man wants MORE caster. How about this idea?

Wouldn't the ball joint have to be relocated, not just the angle changed? With the proper fixtures though, your proposed process would be relatively easy and have minimal knock-on effects. Fewer risks too since the integrity of the arms is retained.

If you're going to this trouble, we just chopsawed the end of the control arm off, weld a flat plate with a 4 bolt chev ball joint thru it.
Support and gusset as nec.
It'll look fabbed, be strong as hell, and ball joint attitude/location is totally up to you.
Just saying, - that's what we did a lotta times.