One absorbs moisture (DOT 3), the other does not (DOT 5). So, what does that mean? It means that with DOT 5, the moisture will not mix with the fluid. So the moisture will be "wherever it is" in the system and OUTSIDE of the DOT 5 brake fluid. So, rust and corrosion "CAN" be an issue. I know, we're now gonna get all the "I've been runnin DOT 5 147 years and never had problems" crowd, but that's the FACT and there's no gettin around it.