Stupid question, but I'm still asking

Would it hurt anything if I paint the potting on the back of an ECU?
In general, painting it will not cause an issue. A heavy enamel, epoxy, or urethane non-metallic paint would likely work best. Coating with more potting compound, or a heavier sealer might do better.

Will it cause heat issues if I do?
Painting or otherwise re-sealing the existing compound will cause no issue to the ECU itself.

Will help to retain the potting if it decides to leave the ECU?
It may retain the potting compound if it has not started to run, but likely only slow it down. If already running, it likely will not stop it, but may still slow it some. Adding epoxy potting to the existing compound will have a better chance of retaining it.

Will it even stick?
It likely will stick on 1970s Chrysler potting compound, and might on later Chrysler ECUs. It depends on the compounds used for aftermarket ECUs. Lightly cleaning and softening the existing potting compound with lacquer thinner or xylene may help promote adhesion.

For some more on the subject of dealing with leaking potting compound, refer to the following:

Chrysler used semi-solid potting compounds in the electronic control units (ECUs), electronic voltage regulators, air conditioning high speed cutout controllers, EGR timers, and other similar electronic modules to protect the internal electronics. In some ECUs and voltage regulators, sand was added to the compound as an additional stiffener for mechanical shock and vibration resistance.

This potting compound can begin oozing or leaking from the back of an ECU, electronic voltage regulator, or other device. The potting compound is not melting, but is slowly breaking down and oozing out. Potting compound has been used for decades in electronics to seal for environmental protection against moisture, debris, etc. and movement of internal components from vibration, mechanical shock, etc. The compounds are typically fast curing two part or single component chemicals that form a solid or semi-solid protective barrier. Over time the compound can break down and "run" or otherwise deteriorate. Heat does not necessarily cause it, but can aggravate the breakdown.

1970s Chrysler ECUs and other assemblies are more susceptible to the oozing than later production parts. Later production was changed to a more rubber-like or silicone-like compound that breaks down less. In general, the parts can continue to function with the compound leaking out unless affected by moisture or other factors. Aftermarket components can also suffer from similar breakdown depending on the nature of their compound. The later units do not really leak the potting because it is an improved composition, typically without the sand. It's easier to clean out too. Most aftermarket units from the 1980s and later are similar. Some are a softer compound, but I have encountered some that seemed harder. Some of the early units from a couple of aftermarket brands do also have sand.

ECUs that have leaked usually still work and can work this way for years. However, exposure of the internal components can lead to corrosion and possible component failure. The leaking ECUs can be cleaned up and re-potted.

These two ECUs were removed from cars in a field. Both are originals that Chrysler installed in the cars. One in 1974, the other in 1976. They both still work but will be cleaned up and re-potted.
PXL_20250126_185954402.MP.jpg

Because it is a chemical degradation, the potting breakdown can occur even when the ECU is not in use on a vehicle. The following image shows a new Autotron ECU, which was sealed in the shrink wrapped box, since 1978, until I opened it the other day. Although not bad, its sticky compound was oozing and stuck to the 1978 newspaper that was used to pack it:
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When the early compound used by Chrysler oozes it forms a sticky mess, and it often has entrained sand, which becomes a sticky sandy mess. Removing the potting is tedious and tricky, especially if trying to not damage the internal components and circuit board. It can be dissolved with lacquer thinner, but it's troublesome to remove from painted surfaces without risking the paint. If the unit has already leaked heavily, that's a head start to removal. Various mechanical means can be used to break away some of the potting if possible. Follow this with application of lacquer thinner. The thinner will dissolve the potting in most cases. In some cases, submerge the unit and let it soak to dissolve the potting inside the case and around the components, but with greater risk to the components. The thinner will eventually dissolve all of the potting, creating a runny, gooey mess. Follow with multiple thinner rinses and manual cleaning to remove the weakened compound. Brake cleaner spray can be for spot cleaning.

If the components are of concern, the lacquer thinner soak can damage them, depending on the amount of exposure. The semiconductors typically will not be affected. The wire wound resistor seems unaffected but the varnish or enamel used on those might weaken. The smaller resistors may lose their markings. The mica capacitors can soften if exposed long enough, and the electrolytic capacitors can start to physically break down depending on the type of construction used. The fiberglass circuit board can become saturated but will dry out.

If there is no concern about the components, just submerge the unit in lacquer thinner and let it sit for a couple of days. It may take a few iterations of soaking and digging to get it cleaned out, but if not concerned about the components, the digging is less tedious.

The lacquer thinner will strip the paint on the few aftermarket units I have done, but it does not really bother the Chrysler units I have done. It seems the black paint may soften some, but a blue unit, and early P4120505 orange units were not fazed. It will remove all markings though, including those on the transistor in many cases. The thinner will not bother the connector or heatsink, but it may weaken the exposed part of the heatsink insulating pad.

After removing the compound, if the case needs refinishing, partially clean it with wire brushing and hand brushing of the case only. If heavier stripping is needed, prior to brushing it, mask the connector and transistor/heatsink, plus cover the back, and carefully bead blast it. The heatsink is anodized aluminum and can be buffed clean if the anodizing is still intact and the aluminum is not corroding. If it is corroding, heavier brushing might be used, but care should be exercised around the insulating pad. The transistor case is nickel plated steel and it can be lightly hand brushed, but any remnants of marking will be gone, and due to its shape, full cleaning of corrosion is difficult.

Evaporust, or similar, can be used in areas that can't be reached with brushing or to get into pits. Some light chemical etching of the external part of the case with phosphoric acid is possible. Don't use the phosphoric acid on the heatsink or transistor. The connector pins can be cleaned with a contact cleaner such as CRC or DeOxit brands. Lacquer thinner can be used for some clean up, especially for any potting on the outside.

The following image shows some ECUs from which I have removed the potting and which will be re-potted when any component repair, further case work, and painting is complete.
PXL_20250126_185805027 (1).jpg

The following image shows "de-potted" ECUs which have been re-painted and tested. I don't attempt to make them look original, just somewhat decently so. Replacement "Electronic Ignition” stickers are available. The repainted ECUs are a P4120505 and an aftermarket version of 4111850. The paint is not the exact color, or sheen, but it's close enough for my use:
PXL_20250126_195549949.jpg

When repainting, don't paint the heatsink, transistor, or connector. I have used a light coat of VHT high temperature clear on the transistor cap to preserve the marking.

After stripping, cleaning, repairing or painting the ECUs, they can be re-potted with an electrically non-conductive, thermally conductive, non-corrosive and waterproof two part (A-B) epoxy compound, such as one of the following:
1757527381470.png1757527393362.png


After re-potting the ECU looks like the one in the following image:
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I test the ECUs units before, during and after the process with a C-4166-A, or more on the lab bench for testing or repair as needed. Real testing is done by running the ECU on a vehicle. I use my 1974 D200 with a 440 and its original ignition wiring with a four terminal dual ballast resistor for functional tests and stress testing of my ECUs.
PXL_20250811_133944563.jpg

Similar rework on 1970+ voltage regulators and police air conditioning cutouts which suffered from potting breakdown and oozing can be done.
PXL_20250127_180813279.jpg
The foregoing excerpt taken from "Chrysler ECU Cleaning and Repair", G. Lewallen, aka Vaanth.