Aluminum Fuel Tanks
In the case of aluminum tanks, aluminum is a highly conductive metal that relies on an oxide layer for its corrosion protection properties. Low levels of ethanol, such as E10 (10%), are usually not a problem in aluminum tanks because the oxide layer provides a good measure of protection. The problem occurs when the ethanol content is increased.
There are two mechanisms that occur with ethanol. Both mechanisms are a result of the hydroscopic property of ethanol, meaning it absorbs water. The more ethanol in the fuel, the more water there will be in the fuel tank. Water not only causes the tank to corrode, it also causes the corrosion particles to clog fuel filters, fuel systems, and damage engine components. The corrosion rate can be accelerated under a number of conditions if other contaminating metals are present such as copper which may be picked up from brass fittings or as a low level contaminant in the aluminum alloy. Chloride, which is a chemical found in salt water, will also accelerate corrosion. In the long term, corrosion can perforate the aluminum to produce leaks that would cause fuel to spill into the bilge and end up in the environment. In the worse case it could cause a fire and/or explosion hazard. Boat fuel tanks are often located under the deck next to the engine where the operator might not be aware of a leak until it was too late. .
The second mechanism that can occurs with the increased use of ethanol based fuel in aluminum tanks is galvanic corrosion. Gasoline fuel is not conductive, but the presence of ethanol or ethanol and water will conduct electricity. The galvanic process that occurs to aluminum trim tabs, stern drives, shaft couplings, etc. will occur within the aluminum fuel tank. Boat builders are able to protect exterior aluminum boat equipment with sacrificial anodes known as zincs. Sacrificial anodes are not a feasible option for the interior of a fuel tank.
