20psi? Please explain psi?
The booster is supposed to be in a state of vacuum, not pressure.
When you step on the pedal, you are opening the atmospheric valve which introduces 14.7 psi atmospheric pressure into the firewall side of the booster. Since this side of the chamber is sealed from the radiator side, which is under vacuum, the diaphragm moves towards the radiator, and applies the brakes, in proportion to how much atmospheric pressure your foot is introducing; and in addition to how hard you are pressing.... if the pushrod is correctly adjusted.
There should be no migration of air or vacuum, between the chambers.
Yes the vacuum in the vacuum chamber will fall, because the chamber is changing volume, as the diaphragm moves towards the radiator. That chamber normally does not require more than 11 to 12 inches of vacuum to make it work.
If your 20 psi, is actually 20 inches vacuum, it should not hurt the diaphragm, but is far in excess of the minimum requirement, and might make the device overly sensitive.
Hissing would be normal AFTER the pedal is released, as the pressure chamber has to be emptied in preparation for the next application. I think the pressure dumps on the firewall side, right next to it, and usually downwards, sometimes sideways.
As far as the minimum vacuum is concerned; I ran the 292/292/108 cam with a single diaphragm booster out of a 73 Dart318 and it worked fine...... even down to 9inches of idle-vacuum. However, this was on a manual trans car with 3.55s. With an MT the driver usually downshifts as he is coming to a stop, so there is always more than say 11 in the chamber. At first start-up in the AM, a couple of blips of the throttle charges the chamber, and by the time I have backed out of my carport, she's good to go.
If your pushrod adjustment is too long, you may be apt to break the control valve on a panick-stop.