Stormy69, you didn't tell us what "synthetic" brake fluid means. I poked around and couldn't find an industry standard definition. It appears that all fluids stating "synthetic" are DOT 4. The reverse is not assured since DOT 4 does not specify the material, but only a standard for properties like boiling point and moisture absorption. To get DOT 4 rating, glycol fluids require additives, which is what "synthetic" probably refers to. I suspect it is more a marketing term.
DOT 5 is a superior rating, and originally only achieved by silicone fluids. However, some glycols mixtures now meet that rating, and are termed DOT 5.1 to distinguish from silicone. Confusing? Since glycol, DOT 5.1 fluids can still rust your brake internals and require flushing every 1-2 years.
My pedals are very stiff with DOT 5 fluid. I have never seen any bubbles in the reservoir. I don't shake the bottle, and I pour it down the side of a funnel, which you should do with any brake fluid.
In my reading, I found that silicone brake fluid is used in very cold climates like Finland and Russia, which seems to disagree with bizarre claims that silicone can be bad because any water can separate and freeze, causing plugs in the brake lines. How does this water get in the system? Glycol fluids suck it in from the atmosphere. I also read bizarre claims that silicone can degrade seals in older brake systems. Hard to believe since it is a pretty benign substance. In counter to that, I read that 50's British racing cars used silicone and that glycol fluids would degrade their seals.
Addendum
In more poking, I hit the mother lode. See
http://adlersantiqueautos.com/articles/brake2.html
A few excerpts:
I called Valvoline and asked which part of the formula was synthetic. The reply was that these glycols are not naturally occurring molecules, so they are synthetic. Emphasizing “synthetic” seems to be a marketing technique rather than unique chemistry.
Paint will still blister upon contact with SynPower® brake fluid. Have a water bucket and sponge ready before starting brake work to immediately dilute and wipe up spills.
Even with its anti-corrosion package and low-moisture-absorbing formula, Valvoline still recommended changing brake fluid every two years, which it felt was about the frequency of brake repairs on vehicles driven daily.
I found other sites that said "synthetic brake fluid" is Valvoline marketing hype. There are no "mineral" brake fluids. It is like selling "inorganic water" or "organic charcoal".