Looks like a 330 Desoto Hemi to me. Early Hemis were true hemis from the drawing board, then they made the car to fit the Hemi. The 426 Hemi valve angles? and valve train was shifted toward the center of the engine to fit the car. Chambers are hemi in both. They are not half a sphere but spherical cut to leave as small a chamber and still get the valves inside the chamber.