Keep in mind that the radiator cap allows pressure to build in your cooling system and per Boyle's Law, PV=nrt all other things remaining the same, a higher pressure will prevent the coolant from boiling at lower temperatures. Said another way, the higher pressure raises the boiling point of the fluid. So if water boils at 212 F at atmospheric pressure (I.e. cap off) with the cap on and pressure built up, water would boil at a higher temperature (240 F hypothetically). Then the larger the temperature difference (called "delta T") the faster the heat transfer will be through the radiator.
Mopar used a 16 psi cap IIRC, so if you have a lower pressure cap, then you have lost some cooling capacity from your system.