Easy. Actually does this outfit have a website, with the destructions posted?
Starting with your photo, where the function knob is pointing the "standard instructions" for measuring an unknown voltage is to always start with the highest setting. Your's does not appear to have an "automatic range" function
The V ----- is supposed to mean DC voltage, the very thing you are measuring.
The highest reading that you can read is 1000V at the top, which is the upper range of the meter. Since you KNOW that the only thing in your car (except ignition spark, which you cannot measure) is 12-15V, set the pointer on 20. This will allow you to measure UP TO 20V on that scale.
In the lower left is the "Omega" sign (the upside down U) means "OHMS" and is for measuring resistance and continuity
200 ohms is "low resistance" and would be used with this meter for measuring form one end to the other on a wire, or maybe a lamp bulb, to check continuity, or even a gas tank sender
Down at the bottom you see the "diode" symbol --->|--- for checking diodes. This is a special function
Turning the know a little more shows "temp C". I assume you would need a special accessory probe to use this, to measure temperature in Celsius degrees
Further left is a "square wave" symbol, I have no idea what that is --RTFM--
R ead T he F u u uc actory Manual
Further left, coming up on the right side is A------
This is for measuring Amperage (current) and the long dashed line means DC current, this meter evidently cannot measure AC current
THIS METER IS TRICKY for measuring amps. For 10 AMPS you would set the meter to "10" and plug one probe into the bottom jack, the other probe goes into the top one marked "10" Can't read it from here
For LOWER amperage measurments, put the probes as they are in the picture, and use the switch.
This meter is marked rather odd. The top scale appears to be 2000 MICRO amps, which is only 2 MILLI amps (2 thoundsandths of one amp)
Second down is 20m and 200m, which is 20 and 200 MILLI amps. 200 milliamps would be .2A or two tenths of an amp
At the very top right corner you have V with the since wave sympol, meaning "volts AC" There's only two scales on this meter, 750 and 200. This means for example, that if you were checking for 220V ac, that is larger than the 200 scale, so you'd have to use the 750 scale.