Sure, you just need some sort of load, and the very easiest way to check would be with a multimeter that has at LEAST a 20A scale, and preferable a 30 or more amp scale.
Coming up with a load, though, might be the tough part. You have a battery charger that can output 20--30A? That would be one way.................. pick one of your cars on which you can access the battery.
Leave the lights on for say, a 1/2 hour with the engine stopped.
Then hook up your battery charger with your multimeter and the car ammeter in series. to charge the battery, and check the car ammeter against your multimeter.
You'll need to take some nuts and make sure the ammeter terminals are firmly tight
I don't remember the scale anymore, seems to me the last mark is 40A
Calibration is not all that important, as long as the needle is free and "repeatable," and stays centered with no current.
Really not much to go wrong, other than bad connections to the shunt inside.