I would like to do some wire repairs using soldered connections instead of the crimp connections that (for me) often fall out no matter how hard I crimp. What is the best type/mix/ratio solder? My past experience soldering wires were not much better than the failed crimps.
Lets break this up. Crimping requires the correct size connector for the wire. The connectors are usually stamped with the wire size. A magnifying lens may needed. Some with insulators are also color coded. Decent crimper helps too and has already been discussed.
A potential disadvantage of soldering is overheating or oversoldering. For this reason a lower melting point solder is generally advantage for electrical and electronic work. Advantage of soldering is a strong joint that moisture can't attack. Bill Grissom's description is good. I'll add a few things FWIW.
I personally like a 25 or 40 watt pencil size soldering iron when working on the car. The radio shack ones are decent for how cheap they are.
The wire must be clean! The metal from both wires or wire and connector must be in good contact with each other. Use a bit of non-corrosive rosin flux. If you're using a flux core solder wire, the flux will melt out first. I think its harder to control but most people seem to prefer flux core.
Alloys: 63/37 or 60/40 are both good for electrical work. Lower flow temperatures mean the least heat transferred to insulation etc.
63/37 is the lowest melting point AND it goes from solid to liquid with no transition. People doing circuit boards and wiring to or near electric motors often will choose this.
All other solder alloys have a temperature range where it is semi-liquid. They needs to get to the full liquid state to flow properly into the wire joint.
60/40 is also used for electric work but it becomes fully liquid at a higher temperature than 63/37.
Wire is spec'd by alloy, wire diameter, how much flux in the wire, and type of flux. Don't let this get you flumexed. For automotive electrical I find a smaller wire diameter is easier to use. Fluxes have a couple different standardized designation systems plus manufacturers description. Just ask the seller if you're not sure.
Approximate melting points from
McMaster-Carr
Sn/Pb Melting Temp (F)
63/37 360
60/40 375
50/50 420
40/60 460
A bunch of information on Kester's website including the
http://www.kester.com/knowledge-base/