-5cc decking is not a form of measurement that I have ever heard of. I'm with txstang84 on this.
In order for a machine shop to theoretically know what -5cc would be after milling the engine block deck surface, they would have to know what piston you were using, because each piston make has a qunique shape and compression distance (distance from center/axis of wrist pin to the top of the piston), which drastically changes volume (in this case, measured in cc)
Since you haven't chosen a piston yet, I don't think any machine shop would have given you any figure, measured in cubic centimeters. Most machine shops won't even give you any figures in cubic centimeters on an SAE engine, unless you are paying them to blueprint the engine for you.
For an example static compression ratio, take the 318 I'm building;
stock 318, overbored .030" (3.940" bore diameter)
stock stroke (3.310" TDC to BDC)
stock rod length (6.123" from the center/ axis of the crank journal to the center/ axis of wrist pin)
stock deck height (9.600")
The piston I'm using has a +5cc set of valve reliefs and a .012" compression distance from the top of the piston, to the top of the block at the deck.
I'm using a head gasket that is .028" thick with a 4.140" diameter.
The heads that I am using have exactly 61cc volume, after I checked them myself.
Without calculating minimal extra volume, like the space between the piston and cylinder wall (usually .002"-.003") and without calculating the distance from the top compression ring to the top of the piston, it leaves me with a static compression ratio of 9.8:1
Dynamic ratio is down somewhere in the 8.2:1 and my actual static at this altitude is somewhere like 8.8:1 because it's at 5460ft elevation, even with 3° advance, on a 235°-240° duration (210° @ .050" lobe lift to lobe lift).
Punch the numbers you have from your parts, into a compression calculator. -
http://www.jeepstrokers.com/calculator/
That calculator has numbers in it for a 4.0L jeep in the fields, but it's the most accurate one I've found online and it only takes a second to overwrite each field.