It's on the same level as plumbing work, sweat the solder in for a good seal.
I prefer to use Lead Solder when I work on anything Cooling or Plumbing related, but it's hard to find good lead solder anymore.
Oh and good Flux/Acid too.
To pressure test it, Clamp a piece of Radiator Hose between the Inlet & Outlet on the radiator, install the Pressure Tester in where the radiator cap goes, pump the pressure up (I usually go 4 pounds more than what my cap is rated for, but you can stop at the cap rating if you want) and then spray the entire radiator with soapy water (dish liquid/soap and water in a spray bottle)
Bubbles means you've got a leak, if you see no bubbles, walk away for a while, tinker on another project and come back later to see if the pressure has bled off. If not, you're good to go.